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001 978-3-662-06431-3
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020 _a9783662064313
_9978-3-662-06431-3
024 7 _a10.1007/978-3-662-06431-3
_2doi
050 4 _aQD146-197
072 7 _aPNK
_2bicssc
072 7 _aSCI013030
_2bisacsh
072 7 _aPNK
_2thema
082 0 4 _a546
_223
100 1 _aMassa, Werner.
_eauthor.
_4aut
_4http://id.loc.gov/vocabulary/relators/aut
245 1 0 _aCrystal Structure Determination
_h[electronic resource] /
_cby Werner Massa.
250 _a2nd ed. 2004.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg :
_bImprint: Springer,
_c2004.
300 _aXI, 212 p.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
505 0 _a1 Introduction -- 2 Crystal Lattices -- 3 The Geometry of X-Ray Diffraction -- 4 The Reciprocal Lattice -- 5 Structure Factors -- 6 Crystal Symmetry -- 7 Experimental Methods -- 8 Structure Solution -- 9 Structure Refinement -- 10 Additional Topics -- 11 Errors and Pitfalls -- 12 Interpretation and Presentation of Results -- 13 Crystallographic Databases -- 14 Outline of a Crystal Structure Determination -- 15 Worked Example of a Structure Determination.
520 _aTo solve a crystal structure means to determine the precise spatial arrangements of all of the atoms in a chemical compound in the crystalline state. This knowledge gives a chemist access to a large range of information, including connectivity, conformation, and accurate bond lengths and angles. In addition, it implies the stoichiometry, the density, the symmetry and the three dimensional packing of the atoms in the solid. Since interatomic distances are in the region of100-300 pm or 1-3 A, 1 microscopy using visible light (wavelength Ä ca. 300-700 nm) is not applicable (Fig. l. l). In 1912, Max von Laue showed that crystals are based on a three dimensionallattice which scatters radiation with a wavelength in the vicinity of interatomic distances, i. e. X -rays with Ä = 50-300 pm. The process bywhich this radiation, without changing its wave­ length, is converted through interference by the lattice to a vast number of observable "reflections" with characteristic directions in space is called X-ray diffraction. The method by which the directions and the intensities of these reflections are measured, and the ordering of the atoms in the crystal deduced from them, is called X-ray struc­ ture analysis. The following chapter deals with the lattice properties of crystals, the starting point for the explanation of these interference phenomena. Interatomic distances Crystals . . . . . . . . . .
650 0 _aInorganic chemistry.
650 0 _aOrganic chemistry.
650 0 _aGeochemistry.
650 0 _aMineralogy.
650 0 _aPhysics.
650 1 4 _aInorganic Chemistry.
_0https://scigraph.springernature.com/ontologies/product-market-codes/C16008
650 2 4 _aOrganic Chemistry.
_0https://scigraph.springernature.com/ontologies/product-market-codes/C19007
650 2 4 _aGeochemistry.
_0https://scigraph.springernature.com/ontologies/product-market-codes/G14003
650 2 4 _aMineralogy.
_0https://scigraph.springernature.com/ontologies/product-market-codes/G38000
650 2 4 _aPhysics, general.
_0https://scigraph.springernature.com/ontologies/product-market-codes/P00002
710 2 _aSpringerLink (Online service)
773 0 _tSpringer Nature eBook
776 0 8 _iPrinted edition:
_z9783642058417
776 0 8 _iPrinted edition:
_z9783540206446
776 0 8 _iPrinted edition:
_z9783662064320
856 4 0 _uhttps://doi.org/10.1007/978-3-662-06431-3
912 _aZDB-2-CMS
912 _aZDB-2-SXC
912 _aZDB-2-BAE
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